Olga Daskali was born in Athens in 1984 and grew up in Messolonghi. She studied at the Law School of Athens and continued her postgraduate studies in Belgium on "European Union, Globalization, Governance". She has postgraduate qualifications in Spatial Planning, Public Management, Adult and Juvenile Education and further training in the field of Cultural Management.

During her student years she was President of AEGEE-Athens and President of the AEGEE-Europe Legal Committee coordinating 240 chapters across Europe.

She is an attorney-at-law, practicing law at the Court of First Instance of Messolonghi.

In the local elections of May 2019, the independent movement "For the Community of Messolonghi" of which she was the leader, came first, and she was elected President of the Community Council of Messolonghi. Today, she is the head of a municipal group planning the transformation of the Municipality of the Holy City of Messolonghi into a modern Municipality, a hub in Western Greece responding to the needs of citizens and visitors.